10







-







-





















-








-





2CO + O2 = 2CO2

10.















128




















10.1).



2,
Fe2O3, SiO2


10.





















10.



























E
E E
k |
|
RT |
(10.1) |
|
|
||
k |
|
RT |
(10.2) |
|
|
||
k |
A |
E |
|
e RT ~ eRT |
(10.3) |
||
k |
A |
|
|











A 


















129

2


10.3). TiO2 
























-






+
2









-



22

















-
























OH












-










O2 (
)
O22- ( ) |
( ) |
- |
|
-



h+
OH
(
)
2




10.














TOF 



turnover frequency







TON 



turnover number).
TOF |
1 N( |
) |
(10.4) |
|
t N( |
) |
|
|
|
-2 |
2 c-1. |
130
TON |
N( |
) |
TOF t , |
(10.5) |
|
N( |
) |
|
|
t 







106 

7





























10.











-














63
H2
3 







2).
2
C












-
-











131














-


















w





) 

















w% |
|
|
|
100 |
|
(10.6) |
( |
3) |
|
|
|
|
(10.7) |
|
|
|
, |
|
|
|
0,14 |
|
|
|
|
|
|
|
|
|
|
: |
|
|
|
C |
2mC |
0,76 10 7 ( / 2 ), |
|
|
(10.8) |
-23 |
|
S |
|
-16 |
2 |
|
|
|
S |
|
|||
mC |
|
|
|
|
|
|
|
|
|
-8 |
|
|
|
|
|
|
. |
|
|
|
1300 2 -1. |
|
|
|
, |
SC = |
~ |
|
|
|
|
|













, 

















, 










SC = 2600
2





























2.





























2









2 





-9 -2
3
132