104 |
3.1.5 Optical materials |
[Ref. p. 131 |
|
x |
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Planes of |
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constant |
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amplitude |
|||
T |
z |
||
n |
n ’ ik ’ |
||
Planes of |
Fig. 3.1.25. Refraction at a medium with absorption: generation |
||
constant |
|||
phase |
of an inhomogeneous wave. |
||
Inhomogeneous wave (Fig. 3.1.25): Snell’s refraction law is modified:
sin ΘT = |
n |
sin Θ |
(3.1.82) |
nT |
|||
with
2 n2T = n 2 − k 2 + n2 sin2 Θ + n 2 − k 2 − n2 sin2 Θ 2 + 4 n 2 k 2 (Ketteler’s formula) .
The e ective refractive index nT determines the direction angle ΘT of planes of constant phase in Fig. 3.1.25 via (3.1.82) [88Kle, p. 78], [41Str, p. 503], [99Bor, p. 740]. The full inhomogeneous wave can be calculated using [99Bor, p. 740].
Example 3.1.11. Θ = 45 ◦, Au: λ = 800 nm, n = 0.19, k = 4.9, nT = 0.73, ΘT = 75.1 ◦ (see [28Koe, p. 209]).
Intensity attenuation in the case Θ = 0 ◦:
I = I0 exp {−2 |
(ω/c) k z} . |
− |
(3.1.83) |
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1/e − depth = 13 nm. |
◦ |
, Au: λ = 800 nm, n |
= 0.19, k |
= 4.9, |
I = I |
0 |
exp |
× |
, |
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Example 3.1.12. Θ |
= 0 |
7.7 |
104 z[mm] |
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p − |
s |
|rs| |
p |
| |
p| |
p |
s |
| |
s| |
s |
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Ellipsometry: δ |
δ |
and moduli |
|rp| |
of the reflected light r |
= |
r |
exp (i δ |
) and r |
= |
r |
exp (i δ |
) |
||||||||||||||||||
can be measured. The complex refractive index of a material results [77Azz, 90Roe]. Application: Measurements for the optical constants of metals, semiconductors, and thin-film systems.
3.1.5.7.1 Classification
The dielectric tensor εr = εij in (1.1.8) is symmetrical and real in the case of a nonabsorbing medium.
In Fig. 3.1.26 vectors connected with wave propagation in crystal optics are depicted. In Table 3.1.8 optical crystals are listed. In Table 3.1.9 three of the eight surfaces for visualization of wave propagation in crystals are presented.
Landolt-B¨ornstein
New Series VIII/1A1
Ref. p. 131] |
3.1 Linear optics |
105 |
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E |
D |
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Beam edge |
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Fig. 3.1.26. Vectors connected with wave propagation in |
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s |
crystal optics [99Bor]: s : ray direction unit vector Poynt- |
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ing vector E × H, n : unit vector in the normal direction |
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B, H |
Beam edge |
n = |
k |
k and phase planes, orthogonalities: B, H E, D, n, s ; |
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k |
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E s ; D n. |
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Table 3.1.8. Optical crystals. |
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Classification: |
Refractive index |
Optical type |
Example |
Values of the |
||||
system (syngony) |
in the main axis |
of crystal |
refractive index |
|||||
of crystal |
system |
for λ = 589.3 nm |
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triclinic, |
nx = ny = nz = nx |
biaxial crystal, no |
NaNO3 |
nx = 1.344 , |
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monoclinic, |
ordinary waves |
ny = 1.411 , |
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orthorhombic |
nz = 1.651 |
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trigonal, |
nx = ny = no |
positive uniaxial |
SiO2 |
no = 1.544, |
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tetragonal, |
(ordinary |
crystal: no < ne |
(quartz) |
ne = 1.553 |
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hexagonal |
index) |
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nx = nz = ne |
negative uniaxial |
CaCO3 |
no = 1.658, |
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(extraordinary |
crystal: no > ne |
(calcite) |
ne = 1.486 |
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index) |
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cubic |
nx = ny = nz = n |
isotropic crystal |
NaCl |
n = 1.544 |
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Table 3.1.9. Three of the eight surfaces for visualization of wave propagation in crystals.
Surface |
Given |
Found by construction are the |
Index ellipsoid (indicatrix) |
normal direction n |
D-vectors for the two polarization cases |
(one-shell surface) |
and the two refractive indices for phase |
|
propagation |
||
Index surface, wave vector |
normal direction n ray directions s, which are perpendicular |
|
surface (two-shell surface) |
to the surface for both polarization cases |
|
Ray surface, wave surface, representing |
ray direction s |
normal direction n, which is perpendicular |
Huygens’ elementary wave for both |
to the surface |
|
polarization cases (two-shell surface) |
||
Main feature of crystal optics: s is not parallel with n for wave propagation, mostly.
–s is essential for description of the energy propagation (edges of bundles, rays),
–n is essential for description of the interferences of infinite broad waves.
References: [28Szi, 54Bel, 58Shu, 61Ram, 76Fed, 79Wah, 84Yar, 04Ber, 99Pau, 99Bor]. A detailed comparison between that surfaces is given in [28Szi].
Landolt-B¨ornstein
New Series VIII/1A1
106 |
3.1.5 Optical materials |
[Ref. p. 131 |
Uniaxial crystals in the plane of incidence:
–Refraction of the normal direction n of wavefronts: The wavevector surface is shown in Fig. 3.1.27.
sin Θo = |
n |
sin Θ (ordinary wave (ko)) |
(3.1.84) |
||
no |
|||||
(no does not depend on the angle of incidence), |
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n |
|||||
sin Θe = |
sin Θ |
(extraordinary wave (ke)) |
(3.1.85) |
||
nθ e (Θe(Θ)) |
|||||
(ne depends on the angle of incidence).
–Refraction of rays (Poynting vector): se and so are given by tangent construction in Fig. 3.1.28.
–Algorithm for the calculation of ko ( so), ke, se of Fig. 3.1.28 with n, no, ne, η, θ of Fig. 3.1.29 [86Haf]:
n2(n2o − n2e )2 sin2 Θ sin2(2η) 2 B2
2 |
n2)2 |
sin Θ sin (2η) |
× n2 sin2 Θ |
(n2 |
n2)2 |
sin2(2η) |
A |
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± |
n(no |
− |
e |
o |
− |
e |
− 1 + |
(3.1.86) |
|||||
B |
B |
||||||||||||
(refractive index for the extraordinary wave)
with
A = (n2e − n2o) n2 sin2 Θ cos (2η) − n2o n2e ,
B = n2o + (n2e − n2o) sin2 η ,
where the decision on the ± sign in (3.1.86) can be made by controlling the satisfaction of
n2θ e n2o + (n2e − n2o) sin2(η + Θe) = n2e n2o .
The resulting angles are: |
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Θo = arcsin(n sin Θ/no) , |
(3.1.87) |
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x |
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Optical axis |
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TE |
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k o |
k e |
TM |
|||||
o e |
z |
||||||
k |
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Polarization |
Fig. 3.1.27. Construction of wavefront birefringence with |
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TE and TM |
|||||||
Index n |
Indices no and ne |
the wavevector surface: The wavefronts show no transversal |
|||||
limitation. |
|||||||
Landolt-B¨ornstein
New Series VIII/1A1
Ref. p. 131] |
3.1 Linear optics |
107 |
Elementary |
||
waves |
||
se |
Extra- |
|
Rays |
ordinary |
|
so |
||
Wavefronts |
||
Ordinary |
||
Optical |
||
axis |
||
Index n |
Indices no and ne |
Index n |
x |
|||
Optical axis |
k oII |
so |
|
k e |
|||
se |
|||
o |
|||
e |
|||
ew |
|||
z |
|||
k II s |
|||
Index n |
Indices no and ne |
||
Fig. 3.1.28. Huygens’ tangent construction of bire- |
Fig. 3.1.29. Refraction for normal and ray direc- |
|||||||||||
fringence in a crystal slab for transversal-limited |
tions. η : angle between z-axis and optical axis. |
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beams. |
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Θe = arcsin (n sin Θ/nΘ e) , |
(3.1.88) |
|||||||||||
Θew = arctan |
tan η − C |
(3.1.89) |
||||||||||
1 + C tan η |
||||||||||||
with |
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n2 |
nΘ2 e |
− |
n2 sin2 Θ tan η + n sin Θ |
|||||||||
C = |
o |
× |
. |
|||||||||
n2 |
||||||||||||
2 |
− n2 sin |
2 |
||||||||||
e |
nΘ e |
Θ − n sin Θ tan η |
||||||||||
Application: Θe, Θo, no, and nΘ e phase di erences (interferences) and reflection coe cient, Θo and Θew ray separation in a crystal.
Example 3.1.13. Calcite: no = 1.658, ne = 1.486, η = 45◦: #1: Θ = 0◦: C = 1.244822, nΘ e = 1.565,
Θo = Θe = 0◦, Θew = −6.224◦; #2: Θ = 45◦: nΘ e = 1.636, C = 0.438329, Θo = 25.23◦, Θe = 25.6◦, Θew = 21.33◦.
General formulation of (3.1.85)–(3.1.89): see [76Fed, Table 9.1] for more detailed discussions.
Starting with the forbidden (stop) bands in case of multi-layer Bragg reflection [88Yeh, p. 123] a material class is under development which stops light propagation along as many directions and for as many wavelengths as possible. This suppresses the spontaneous emission for laser applications and opens new possibilities in the microand nano-optics [95Joa, 01Sak, 04Bus]. Photonic crystal fibers [04Bus] can be designed for special light propagation properties and high-power fiber lasers [03Wad].
Landolt-B¨ornstein
New Series VIII/1A1
108 |
3.1.6 Geometrical optics |
[Ref. p. 131 |
The common excitation of electrical dipoles and magnetical dipoles by light in a medium can result in a negative dielectric permittivity Re (ε) < 0 in combination with a negative magnetic permeability Re (µ) < 0 . Then, in Snell’s law (3.1.72) an e ective index nˆ < 0 is possible [68Ves] which results in imaging by a slab of this material without curved surfaces [00Pen] and other interesting e ects [05Ram]. Such metamaterials can be generated by microtechnology, now for mmand terahertz-waves, but with the trend towards visible radiation [05Ele].
[62Lan] contains optical constants, only. In later editions, the optical constants are listed together with other properties of substances. An overview is given in the content volume [96Lan].
Optical glass: |
[62Lan, Chap. 283], [97Nik], [95Bas, Vol. 2, Chap. 33], cat- |
alogs of producers: [96Sch, 98Hoy, 96Oha, 92Cor], and com- |
|
mercial optical design programs. |
|
Infrared materials: |
[98Pal, 91Klo], [96Sch, infrared glasses], commercial optical |
design programs. |
|
Crystals: |
[62Lan, Chap. 282], [95Bas, Vol. 2, Chap. 33], [97Nik, 91Dmi, |
81Kam]. |
|
Photonic crystals: |
[95Joa, 01Sak, 04Bus]. |
Negative-refractive-index materials: |
[05Ram]. |
Polymeric materials: |
[62Lan, Chap. 283], [95Bas, Vol. 2, Chap. 34], [97Nik]. |
Metals: |
[62Lan, Chap. 281], [98Pal], [95Bas, Vol. 2, Chap. 35]. |
Semiconductors: |
[96Lan, 98Pal, 87EMI], [95Bas, Vol. 2, Chap. 36]. |
Solid state laser materials: |
[01I , 97Nik, 81Kam]. |
Liquids: |
[62Lan, Chaps. 284, 285], [97Nik]. |
Gases: |
[62Lan, Chap. 286]. |
3.1.6 Geometrical optics
Geometrical optics represents the limit of the wave optics for λ 0 .
The development sin σ = σ − 3!1 σ3 + 5!1 σ5 − . . . with σ the angle in Snell’s law characterizes the di erent approaches of geometrical optics. Table 3.1.10 gives an overview of di erent approximations of geometrical optics.
The signs of the parameters determined in [03DIN, 96Ped] are applied in Sect. 3.1.6.1.1, later on f = f is used.
Landolt-B¨ornstein
New Series VIII/1A1