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104

3.1.5 Optical materials

[Ref. p. 131

x

Planes of

constant

amplitude

T

z

n

n ’ ik ’

Planes of

Fig. 3.1.25. Refraction at a medium with absorption: generation

constant

phase

of an inhomogeneous wave.

Inhomogeneous wave (Fig. 3.1.25): Snell’s refraction law is modified:

sin ΘT =

n

sin Θ

(3.1.82)

nT

with

2 n2T = n 2 − k 2 + n2 sin2 Θ + n 2 − k 2 − n2 sin2 Θ 2 + 4 n 2 k 2 (Ketteler’s formula) .

The e ective refractive index nT determines the direction angle ΘT of planes of constant phase in Fig. 3.1.25 via (3.1.82) [88Kle, p. 78], [41Str, p. 503], [99Bor, p. 740]. The full inhomogeneous wave can be calculated using [99Bor, p. 740].

Example 3.1.11. Θ = 45 ◦, Au: λ = 800 nm, n = 0.19, k = 4.9, nT = 0.73, ΘT = 75.1 ◦ (see [28Koe, p. 209]).

Intensity attenuation in the case Θ = 0 ◦:

I = I0 exp {−2

(ω/c) k z} .

−

(3.1.83)

1/e − depth = 13 nm.

◦

, Au: λ = 800 nm, n

= 0.19, k

= 4.9,

I = I

0

exp

×

,

Example 3.1.12. Θ

= 0

7.7

104 z[mm]

p −

s

|rs|

p

|

p|

p

s

|

s|

s

Ellipsometry: δ

δ

and moduli

|rp|

of the reflected light r

=

r

exp (i δ

) and r

=

r

exp (i δ

)

can be measured. The complex refractive index of a material results [77Azz, 90Roe]. Application: Measurements for the optical constants of metals, semiconductors, and thin-film systems.

3.1.5.7 Crystal optics

3.1.5.7.1 Classification

The dielectric tensor εr = εij in (1.1.8) is symmetrical and real in the case of a nonabsorbing medium.

In Fig. 3.1.26 vectors connected with wave propagation in crystal optics are depicted. In Table 3.1.8 optical crystals are listed. In Table 3.1.9 three of the eight surfaces for visualization of wave propagation in crystals are presented.

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New Series VIII/1A1

Ref. p. 131]

3.1 Linear optics

105

E

D

Beam edge

Fig. 3.1.26. Vectors connected with wave propagation in

s

crystal optics [99Bor]: s : ray direction unit vector Poynt-

ing vector E × H, n : unit vector in the normal direction

B, H

Beam edge

n =

k

k and phase planes, orthogonalities: B, H E, D, n, s ;

k

E s ; D n.

Table 3.1.8. Optical crystals.

Classification:

Refractive index

Optical type

Example

Values of the

system (syngony)

in the main axis

of crystal

refractive index

of crystal

system

for λ = 589.3 nm

triclinic,

nx = ny = nz = nx

biaxial crystal, no

NaNO3

nx = 1.344 ,

monoclinic,

ordinary waves

ny = 1.411 ,

orthorhombic

nz = 1.651

trigonal,

nx = ny = no

positive uniaxial

SiO2

no = 1.544,

tetragonal,

(ordinary

crystal: no < ne

(quartz)

ne = 1.553

hexagonal

index)

nx = nz = ne

negative uniaxial

CaCO3

no = 1.658,

(extraordinary

crystal: no > ne

(calcite)

ne = 1.486

index)

cubic

nx = ny = nz = n

isotropic crystal

NaCl

n = 1.544

Table 3.1.9. Three of the eight surfaces for visualization of wave propagation in crystals.

Surface

Given

Found by construction are the

Index ellipsoid (indicatrix)

normal direction n

D-vectors for the two polarization cases

(one-shell surface)

and the two refractive indices for phase

propagation

Index surface, wave vector

normal direction n ray directions s, which are perpendicular

surface (two-shell surface)

to the surface for both polarization cases

Ray surface, wave surface, representing

ray direction s

normal direction n, which is perpendicular

Huygens’ elementary wave for both

to the surface

polarization cases (two-shell surface)

Main feature of crystal optics: s is not parallel with n for wave propagation, mostly.

–s is essential for description of the energy propagation (edges of bundles, rays),

–n is essential for description of the interferences of infinite broad waves.

References: [28Szi, 54Bel, 58Shu, 61Ram, 76Fed, 79Wah, 84Yar, 04Ber, 99Pau, 99Bor]. A detailed comparison between that surfaces is given in [28Szi].

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New Series VIII/1A1

4B2
n2θ e
= BA +

106

3.1.5 Optical materials

[Ref. p. 131

3.1.5.7.2 Birefringence (example: uniaxial crystals)

Uniaxial crystals in the plane of incidence:

–Refraction of the normal direction n of wavefronts: The wavevector surface is shown in Fig. 3.1.27.

sin Θo =

n

sin Θ (ordinary wave (ko))

(3.1.84)

no

(no does not depend on the angle of incidence),

n

sin Θe =

sin Θ

(extraordinary wave (ke))

(3.1.85)

nθ e (Θe(Θ))

(ne depends on the angle of incidence).

–Refraction of rays (Poynting vector): se and so are given by tangent construction in Fig. 3.1.28.

–Algorithm for the calculation of ko ( so), ke, se of Fig. 3.1.28 with n, no, ne, η, θ of Fig. 3.1.29 [86Haf]:

n2(n2o − n2e )2 sin2 Θ sin2(2η) 2 B2

2

n2)2

sin Θ sin (2η)

× n2 sin2 Θ

(n2

n2)2

sin2(2η)

A

±

n(no

−

e

o

−

e

− 1 +

(3.1.86)

B

B

(refractive index for the extraordinary wave)

with

A = (n2e − n2o) n2 sin2 Θ cos (2η) − n2o n2e ,

B = n2o + (n2e − n2o) sin2 η ,

where the decision on the ± sign in (3.1.86) can be made by controlling the satisfaction of

n2θ e n2o + (n2e − n2o) sin2(η + Θe) = n2e n2o .

The resulting angles are:

Θo = arcsin(n sin Θ/no) ,

(3.1.87)

x

Optical axis

TE

k o

k e

TM

o e

z

k

Polarization

Fig. 3.1.27. Construction of wavefront birefringence with

TE and TM

Index n

Indices no and ne

the wavevector surface: The wavefronts show no transversal

limitation.

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New Series VIII/1A1

Ref. p. 131]

3.1 Linear optics

107

Elementary

waves

se

Extra-

Rays

ordinary

so

Wavefronts

Ordinary

Optical

axis

Index n

Indices no and ne

Index n

x

Optical axis

k oII

so

k e

se

o

e

ew

z

k II s

Index n

Indices no and ne

Fig. 3.1.28. Huygens’ tangent construction of bire-

Fig. 3.1.29. Refraction for normal and ray direc-

fringence in a crystal slab for transversal-limited

tions. η : angle between z-axis and optical axis.

beams.

Θe = arcsin (n sin Θ/nΘ e) ,

(3.1.88)

Θew = arctan

tan η − C

(3.1.89)

1 + C tan η

with

n2

nΘ2 e

−

n2 sin2 Θ tan η + n sin Θ

C =

o

×

.

n2

2

− n2 sin

2

e

nΘ e

Θ − n sin Θ tan η

Application: Θe, Θo, no, and nΘ e phase di erences (interferences) and reflection coe cient, Θo and Θew ray separation in a crystal.

Example 3.1.13. Calcite: no = 1.658, ne = 1.486, η = 45◦: #1: Θ = 0◦: C = 1.244822, nΘ e = 1.565,

Θo = Θe = 0◦, Θew = −6.224◦; #2: Θ = 45◦: nΘ e = 1.636, C = 0.438329, Θo = 25.23◦, Θe = 25.6◦, Θew = 21.33◦.

General formulation of (3.1.85)–(3.1.89): see [76Fed, Table 9.1] for more detailed discussions.

3.1.5.8 Photonic crystals

Starting with the forbidden (stop) bands in case of multi-layer Bragg reflection [88Yeh, p. 123] a material class is under development which stops light propagation along as many directions and for as many wavelengths as possible. This suppresses the spontaneous emission for laser applications and opens new possibilities in the microand nano-optics [95Joa, 01Sak, 04Bus]. Photonic crystal fibers [04Bus] can be designed for special light propagation properties and high-power fiber lasers [03Wad].

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New Series VIII/1A1

108

3.1.6 Geometrical optics

[Ref. p. 131

3.1.5.9 Negative-refractive-index materials

The common excitation of electrical dipoles and magnetical dipoles by light in a medium can result in a negative dielectric permittivity Re (ε) < 0 in combination with a negative magnetic permeability Re (µ) < 0 . Then, in Snell’s law (3.1.72) an e ective index nˆ < 0 is possible [68Ves] which results in imaging by a slab of this material without curved surfaces [00Pen] and other interesting e ects [05Ram]. Such metamaterials can be generated by microtechnology, now for mmand terahertz-waves, but with the trend towards visible radiation [05Ele].

3.1.5.10 References to data of linear optics

[62Lan] contains optical constants, only. In later editions, the optical constants are listed together with other properties of substances. An overview is given in the content volume [96Lan].

Optical glass:

[62Lan, Chap. 283], [97Nik], [95Bas, Vol. 2, Chap. 33], cat-

alogs of producers: [96Sch, 98Hoy, 96Oha, 92Cor], and com-

mercial optical design programs.

Infrared materials:

[98Pal, 91Klo], [96Sch, infrared glasses], commercial optical

design programs.

Crystals:

[62Lan, Chap. 282], [95Bas, Vol. 2, Chap. 33], [97Nik, 91Dmi,

81Kam].

Photonic crystals:

[95Joa, 01Sak, 04Bus].

Negative-refractive-index materials:

[05Ram].

Polymeric materials:

[62Lan, Chap. 283], [95Bas, Vol. 2, Chap. 34], [97Nik].

Metals:

[62Lan, Chap. 281], [98Pal], [95Bas, Vol. 2, Chap. 35].

Semiconductors:

[96Lan, 98Pal, 87EMI], [95Bas, Vol. 2, Chap. 36].

Solid state laser materials:

[01I , 97Nik, 81Kam].

Liquids:

[62Lan, Chaps. 284, 285], [97Nik].

Gases:

[62Lan, Chap. 286].

3.1.6 Geometrical optics

Geometrical optics represents the limit of the wave optics for λ 0 .

The development sin σ = σ − 3!1 σ3 + 5!1 σ5 − . . . with σ the angle in Snell’s law characterizes the di erent approaches of geometrical optics. Table 3.1.10 gives an overview of di erent approximations of geometrical optics.

3.1.6.1 Gaussian imaging (paraxial range)

The signs of the parameters determined in [03DIN, 96Ped] are applied in Sect. 3.1.6.1.1, later on f = f is used.

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New Series VIII/1A1

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