Материал: Андрианова English Thesaurus of Student-Physicist 2013

During the day, the Sun adds roughly equal amounts of energy to the beach and the water, but the lower specific heat of sand causes the beach to reach a higher temperature than the water. As a result, the air above the land reaches a higher temperature than the air above the water. The denser cold air pushes the less dense hot air upward (due to Archimedes's principle), resulting in a breeze from ocean to land during the day.

Calorimetry

One technique for measuring the specific heat of a solid or liquid is to raise the temperature of the substance to some value, place it into a vessel containing cold water of known mass and temperature, and measure the temperature of the combination after equilibrium is reached. Define the system as the substance and the water. If the vessel is assumed to be a good insulator, so that energy doesn't leave the system, then we can assume the system is isolated. Vessels having this property are called calorimeters, and analysis performed using such vessels is called calorimetry.

The principle of conservation of energy for this isolated system requires that the net result of all energy transfers is zero. If one part of the system loses energy, another part has to gain the energy, because the system is isolated and the energy has nowhere else to go. When a warm object is placed in the cooler water of a calorimeter, the warm object becomes cooler while the water becomes warmer.

Latent heat and phase change

A substance usually undergoes a change in temperature when energy is transferred between the substance and its environment. In some cases, however, the transfer of energy doesn't result in a change in temperature. This can occur when the physical characteristics of the substance change from one form to another, commonly referred to as a phase change. Some common phase changes are solid to liquid (melting), liquid to gas (boiling), and a change in the crystalline structure of a solid. Any such phase change involves a change in the internal energy, but no change in the temperature.

Latent heat of the substance, depends on the nature of the phase change. The unit of latent heat is the joule per kilogram (J/kg). The latent heat of fusion is used when a phase change occurs during melting or freezing, while the latent heat of vaporization is used when a phase change oc-

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curs during boiling or condensing. When a gas cools, it eventually returns to the liquid phase, or condenses. The energy per unit mass given up during the process is called the heat of condensation, and it equals the heat of vaporization. When a liquid cools, it eventually solidifies, and the heat of solidification equals the heat of fusion.

Global warming and greenhouse gases

Many of the principles of energy transfer, and opposition to it, can be understood by studying the operation of a glass greenhouse. During the day, sunlight passes into the greenhouse and is absorbed by the walls, soil, plants, and so on. This absorbed visible light is subsequently reradiated as infrared radiation, causing the temperature of the interior to rise.

In addition, convection currents are inhibited in a greenhouse. As a result, warmed air can't rapidly pass over the surfaces of the greenhouse that are exposed to the outside air and thereby cause an energy loss by conduction through those surfaces.

A phenomenon commonly known as the greenhouse effect can also play a major role in determining the Earth's temperature. First, note that the Earth's atmosphere is a good transmitter (and hence a poor absorber) of visible radiation and a good absorber of infrared radiation. The visible light that reaches the Earth's surface is absorbed and reradiated as infrared light, which in turn is absorbed (trapped) by the Earth's atmosphere. An extreme case is the warmest planet, Venus, which has a carbon dioxide (CO2) atmosphere and temperatures approaching 850°F.

1.What happens when two objects with different temperatures are placed in thermal contact?

2.What kinds of energy does internal energy include?

3.Give the definition of calorie.

4.What vessels are called calorimeters?

5.What kinds of phase changes do you know?

6.What do you know about global warming?

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Exercises

1. Rearrange the letters in the anagrams to form equivalents for the Russian words:

2. Match the words in A with the words in B to form word combinations:

3. Fill in the gaps with the missing words from the list:

British thermal unit (Btu), internal energy, greenhouse gases, heat, specific heat

1.The _____ of a monatomic ideal gas is associated with the translational motion of its atoms.

2._____ is the transfer of thermal energy, just as work is the transfer of mechanical energy.

3.The unit of heat in the U.S. customary system, the _____, was defined as the energy required to raise the temperature of 1 lb of water from 63°F to 64°F.

4.The fact that the _____ of water is higher than the specific heat of sand is responsible for the pattern of airflow at a beach.

5.Whether the increasing _____ are responsible or not, there is convincing evidence that global warming is underway.

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UNIT 12

THE LAWS OF THERMODINAMICS

Read the following texts. Study the thesaurus on fig. 12, answer the questions after the texts

According to the first law of thermodynamics, the internal energy of a system can be increased either by adding energy to the system or by doing work on it. This means the internal energy of a system, which is just the sum of the molecular kinetic and potential energies, can change as a result of two separate types of energy transfer across the boundary of the system. Although the first law imposes conservation of energy for both energy added by heat and work done on a system, it doesn't predict which of several possible energy-conserving processes actually occur in nature.

The second law of thermodynamics constrains the first law by establishing which processes allowed by the first law actually occur. For example, the second law tells us that energy never flows by heat spontaneously from a cold object to a hot object. One important application this law is in the study of heat engines (such as the internal combustion engine) and the principles that limit their efficiency.

Work in thermodynamic processes

Energy can be transferred to a system by heat and by work done on the system. In most cases of interest treated here, the system is a volume of gas, which is important in understanding engines. All such systems of gas will be assumed to be in thermodynamic equilibrium, so that every part of the gas is at the same temperature and pressure. If that were not the case, the ideal gas law wouldn't apply and most of the results presented here wouldn't be valid.

The first law of thermodynamics

The first law of thermodynamics is another energy conservation law that relates changes in internal energy - the energy associated with the position and jiggling of all the molecules of a system - to energy transfers due to heat and work. The first law is universally valid, applicable to all kinds of processes, providing a connection between the microscopic and macroscopic worlds.

There are two ways energy can be transferred between a system and its surroundings: by doing work, which requires a macroscopic dis-

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placement of an object through the application of a force; and by heat, which occurs through random molecular collisions. Both mechanisms result in a change in internal energy, of the system and therefore in measurable changes in the macroscopic variables of the system, such as the pressure, temperature, and volume. The energy transferred to the system is positive when energy is transferred into the system by heat and negative when energy is transferred out of the system by heat.

A gas with a larger molar specific heat requires more energy to realize a given temperature change. The size of the molar specific heat depends on the structure of the gas molecule and how many different ways it can store energy. A monatomic gas such as helium can store energy as motion in three different directions. A gas such as hydrogen, on the other hand, is diatomic in normal temperature ranges, and aside from moving in three directions, it can also tumble, rotating in two different directions. So hydrogen molecules can store energy in the form of translational motion, and in addition can store energy through tumbling. Molecules can also store energy in the vibrations of their constituent atoms. A gas composed of molecules with more ways to store energy will have a larger molar specific heat.

There are four basic types of thermal processes. In an isobaric process the pressure remains constant as the gas expands or is compressed. Expanding volume and decreasing temperature means the pressure must also decrease, in conformity with the ideal gas law. In the adiabatic process, no energy enters or leaves the system by heat. Such a system is insulated - thermally isolated from its environment. An adiabatic expansion is of practical importance and is nearly realized in an internal combustion engine. An isovolumetric process, sometimes called an isochoric process, proceeds at constant volume. In an isochoric process, the change in internal energy of a system equals the energy transferred to the system by heat. During an isothermal process the temperature of a system doesn't change. If the system is an ideal gas undergoing an isothermal process, the work done on the system is equal to the negative of the thermal energy transferred to the system.

Heat engines and the second law of thermodynamics

A heat engine takes in energy by heat and partially converts it to other forms, such as electrical and mechanical energy. In a typical process for producing electricity in a power plant, for instance, coal or some other fuel is burned, and the resulting internal energy is used to convert

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